Classic Oils Anti-Freeze Safety Data Sheet


Compilation date:  05/03/2021
 
Section 1: Identification of the substance/mixture and of the company/undertaking
 
1.1. Product identifier
 
Product name:  Classic Oils 2-Year Blue Anti-Freeze
 
Product code:  N/A
 
1.2. Relevant identified uses of the substance or mixture and uses advised against
 
Use of substance / mixture:  PC4: Anti-Freeze and de-icing products.
 
1.3. Details of the supplier of the safety data sheet
 
Company name:  Classic Oils Ltd
Building 96
The Lubricant Store Bicester Heritage
Buckingham Road
Bicester
Oxon
OX26 8AL
United Kingdom
Tel:  01869 227062
 
Email:   sales@classic-oils.net
 
1.4. Emergency telephone number
 
Emergency tel:  01869 227062
 
Section 2: Hazards identification
 
2.1. Classification of the substance or mixture
 
Classification under CLP:  Acute Tox. 4: H302; STOT RE 2: H373
Most important adverse effects:  Harmful if swallowed. May cause damage to organs through prolonged or repeated exposure ([oral]).
 
2.2. Label elements
 
Label elements:
 
Hazard statements:  H302: Harmful if swallowed.
 
H373: May cause damage to organs through prolonged or repeated exposure ([oral]).
 
Hazard pictograms:  

GHS07: Exclamation mark
 
GHS08: Health hazard
 
 
Signal words:  Warning
 
Precautionary statements:  P260: Do not breathe dust/fumes/gas/mist/vapours/spray.
 
P264: Wash hands thoroughly after handling.

P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor. P330: Rinse mouth.
P501: Dispose of contents/container to an authorised waste disposal contractor.
 
2.3. Other hazards
 
PBT:  This product is not identified as a PBT/vPvB substance.
 
Section 3: Composition/information on ingredients
 
3.2. Mixtures
 
 
Hazardous ingredients:
 
MONO ETHYLENE GLYCOL - REACH registered number(s): 01-2119456816-28
 
EINECS CAS PBT / WEL CLP Classification Percent
203-473-3 107-21-1 - Acute Tox. 4: H302; STOT RE 2: H373 >90%
 
DISODIUM TETRABORATE, ANHYDROUS
 
215-540-4 1330-43-4 - Repr. 1B: H360FD 1-10%
 
Section 4: First aid measures
 
4.1. Description of first aid measures
 
Skin contact:  Wash immediately with plenty of soap and water.
 
Eye contact:  Bathe the eye with running water for 15 minutes.
 
Ingestion:  Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Transfer to hospital as soon as possible.
Inhalation:  Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor.
 
4.2. Most important symptoms and effects, both acute and delayed
 
Skin contact:  There may be mild irritation at the site of contact.
 
Eye contact:  There may be irritation and redness.
 
Ingestion:  There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation:  Absorption through the lungs can occur causing symptoms similar to those of ingestion.
 
Delayed / immediate effects:  Immediate effects can be expected after short-term exposure.
 
4.3. Indication of any immediate medical attention and special treatment needed
 
Immediate / special treatment:  Not applicable.
 
Section 5: Fire-fighting measures
 

5.1. Extinguishing media
 
Extinguishing media:  Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.
 
5.2. Special hazards arising from the substance or mixture
 
Exposure hazards:  In combustion emits toxic fumes.
 
5.3. Advice for fire-fighters
 
Advice for fire-fighters:  Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
 
Section 6: Accidental release measures
 
6.1. Personal precautions, protective equipment and emergency procedures
 
Personal precautions:  Refer to section 8 of SDS for personal protection details. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers
leak-side up to prevent the escape of liquid.
 
6.2. Environmental precautions
 
Environmental precautions:  Do not discharge into drains or rivers. Contain the spillage using bunding.
 
6.3. Methods and material for containment and cleaning up
 
Clean-up procedures:  Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
 
6.4. Reference to other sections
 
Reference to other sections:  Refer to section 8 of SDS.
 
Section 7: Handling and storage
 
7.1. Precautions for safe handling
 
Handling requirements:  Avoid the formation or spread of mists in the air. Avoid direct contact with the substance.
 
7.2. Conditions for safe storage, including any incompatibilities
 
Storage conditions:  Store in a cool, well ventilated area. Keep container tightly closed.
 
7.3. Specific end use(s)
 
Specific end use(s):  No data available.
 
Section 8: Exposure controls/personal protection
 
8.1. Control parameters
 
 
 
Workplace exposure limits:

Respirable dust
 
 
State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL
EU 60 125 - -
 
 
Hazardous ingredients:
 
MONO ETHYLENE GLYCOL
 
 
Workplace exposure limits:

Respirable dust
 
 
State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL
EU 20 ppm (Sk) 40 ppm (Sk) - -
 
DNEL/PNEC Values
 
 
OPTICOOL ANTIFREEZE BLUE
 
Type Exposure Value Population Effect
DNEL Inhalation 35 mg/m3 Workers Local
DNEL Dermal 106 mg/kg Workers Systemic
DNEL Inhalation 7 mg/m3 Consumers Local
DNEL Dermal 53 mg/m3 Consumers Systemic
PNEC Fresh water 10 mg/l - -
PNEC Marine water 1 mg/l - -
PNEC Fresh water sediments 20.9 mg/kg - -
PNEC Soil (agricultural) 1.53 mg/kg - -
 
 
Hazardous ingredients:
 
MONO ETHYLENE GLYCOL
 
Type Exposure Value Population Effect
DNEL Inhalation 35 mg/m3 Workers Local
DNEL Dermal 106 mg/kg Workers Systemic
DNEL Inhalation 7 mg/m3 Consumers Local
DNEL Dermal 53 mg/m3 Consumers Systemic
PNEC Fresh water 10 mg/l - -
PNEC Marine water 1 mg/l - -
PNEC Microorganisms in sewage treatment 199.5 mg/l - -
PNEC Fresh water sediments 20.9 mg/kg - -
PNEC Soil (agricultural) 1.53 mg/kg - -
 
8.2. Exposure controls
 
Respiratory protection:  Respiratory protection not required.
 
Hand protection:  Protective gloves.
 

Eye protection:  Safety glasses. Ensure eye bath is to hand.
 
Skin protection:  Protective clothing.
 
Section 9: Physical and chemical properties
 
9.1. Information on basic physical and chemical properties
 
State:  Liquid Colour:  Blue Odour:  Odourless
Evaporation rate:  No data available.
 
Oxidising:  No data available.
 
Solubility in water:  Miscible
 
Viscosity:  Non-viscous
 
Kinematic viscosity:  21
 
Viscosity test method:  cP @ 20°C
 
Boiling point/range°C:  165                                                                       Melting point/range°C:  -12
 
Flammability limits %: lower:  No data available.                                                                            upper:  No data available.
 
Flash point°C:  111                                                              Part.coeff. n-octanol/water:  log Pow -1.93
 
Autoflammability°C:  400                                                                                 Vapour pressure:  0.05 kPa
 
Relative density:  1.13 @ 20 deg C                                                                                    pH:  No data available.
 
VOC g/l:  No data available.
 
9.2. Other information
 
Other information:  No data available.
 
Section 10: Stability and reactivity
 
10.1. Reactivity
 
Reactivity:  Stable under recommended transport or storage conditions.
 
10.2. Chemical stability
 
Chemical stability:  Stable under normal conditions.
 
10.3. Possibility of hazardous reactions
 
Hazardous reactions:  Hazardous reactions will not occur under normal transport or storage conditions.
 
Decomposition may occur on exposure to conditions or materials listed below.
 
10.4. Conditions to avoid
 
Conditions to avoid:  Heat.
 
10.5. Incompatible materials
 
Materials to avoid:  Strong oxidising agents. Strong acids.
 
10.6. Hazardous decomposition products
 
Haz. decomp. products:  In combustion emits toxic fumes.
 

Section 11: Toxicological information
 
11.1. Information on toxicological effects
 
 
Toxicity values:
 
Route Species Test Value Units
ORAL RAT LD50 7,712 mg/kg
DERMAL MUS LD50 3,500 mg/kg
VAPOURS RAT 4H LC50 2.5 mg/l
 
 
Relevant hazards for product:
 
Hazard Route Basis
Acute toxicity (ac. tox. 4) ING Hazardous: calculated
STOT-repeated exposure - Hazardous: calculated
 
Symptoms / routes of exposure
 
Skin contact:  There may be mild irritation at the site of contact.
 
Eye contact:  There may be irritation and redness.
 
Ingestion:  There may be soreness and redness of the mouth and throat. There may be difficulty swallowing. Nausea and stomach pain may occur. There may be vomiting.
Inhalation:  Absorption through the lungs can occur causing symptoms similar to those of ingestion.
 
Delayed / immediate effects:  Immediate effects can be expected after short-term exposure.
 
Section 12: Ecological information
 
12.1. Toxicity
 
 
Ecotoxicity values:
 
Species Test Value Units
FISH 96H LC50 72860 mg/l
Daphnia magna 48H EC50 >100 mg/l
GREEN ALGA (Selenastrum capricornutum) 96H ErC50 >6500 mg/l
 
12.2. Persistence and degradability
 
Persistence and degradability:  Biodegradable.
 
12.3. Bioaccumulative potential
 
Bioaccumulative potential:  No bioaccumulation potential.
 
12.4. Mobility in soil
 
Mobility:  Readily absorbed into soil.
 
12.5. Results of PBT and vPvB assessment
 
PBT identification:  This product is not identified as a PBT/vPvB substance.


12.6. Other adverse effects
 
Other adverse effects:  Negligible ecotoxicity.
 
Section 13: Disposal considerations
 
13.1. Waste treatment methods
 
Disposal operations:  Transfer to a suitable container and arrange for collection by specialised disposal company.
NB:  The user's attention is drawn to the possible existence of regional or national
 
regulations regarding disposal.
 
Section 14: Transport information
 
Transport class:  This product does not require a classification for transport.
 
Section 15: Regulatory information
 
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
 
Specific regulations:  Not applicable.
 
15.2. Chemical Safety Assessment
 
Chemical safety assessment:  A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.
 
Section 16: Other information
 
Other information
 
Other information:  This safety data sheet is prepared in accordance with Commission Regulation (EU) No
 
2015/830.
 
Phrases used in s.2 and s.3:  H302: Harmful if swallowed.
 
H360FD: May damage fertility. May damage the unborn child.
 
H373: May cause damage to organs ([kidneys]) through prolonged or repeated exposure ([oral]).
 
H373: May cause damage to organs through prolonged or repeated exposure ([oral]).
 
Legal disclaimer:  The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.